PSA hydrogen purification

PSA HYDROGEN PURIFICATION

Hydrogen purification molecular sieve solutions for PSA

JALON delivers high-performance hydrogen purification molecular sieve solutions for PSA applications—helping industrial operators remove key impurities, protect downstream processes and produce reliable high-purity hydrogen.

JLWN5 Molecular Sieve

High adsorption capacity, rapid adsorption/desorption and high mechanical strength for hydrogen purification applications.

Convert hydrogen-rich feed gas into reliable product gas

Hydrogen from reforming, refinery and chemical processes commonly contains carbon oxides, nitrogen, methane, moisture and residual hydrocarbons. PSA purification selectively removes these impurities while allowing hydrogen to pass through as product gas.

How PSA hydrogen purification works

01 FEED GAS

Hydrogen-rich feed

H₂ enters the unit with process-specific impurities.

02 ADSORPTION

Impurities retained

Adsorbent layers selectively retain non-hydrogen components.

03 REGENERATION

Bed restored

Pressure reduction releases impurities for the next cycle.

04 PRODUCT H₂

Continuous output

Multiple beds cycle in sequence for continuous product flow.

Designed for demanding hydrogen-rich feeds

PSA is widely applied to hydrogen streams from steam methane reforming, refinery and petrochemical off-gases, coke oven gas, and methanol or ammonia off-gases.

Target the impurities that limit hydrogen quality

JLWN5 is designed for CO, N₂ and CH₄ removal in an H₂ PSA adsorption bed. For feeds carrying higher moisture, CO₂ or heavy hydrocarbons, it can be combined with appropriate upstream protection layers.

OUR SOLUTION

JLWN5: A 5A molecular sieve recommended for PSA hydrogen purification

JLWN5 is a synthetic crystalline aluminosilicate with a well-developed three-dimensional pore structure and strong polarity, with a pore opening of 0.5nm. Enabled by a superior formation process, JLWN5 greatly increased the CO, N2, and CH4 adsorption capacity compared with standard molecular sieve 5A. 

Designed with the advantages of a large adsorption capacity, fast adsorption & desorption rate and high mechanical strength, JLWN5 is an excellent adsorbent for the PSA hydrogen purification process.

Beyond hydrogen purification, JLWN5 can also be used to separate normal paraffins from branched and cyclic hydrocarbons and for air drying.

JLWN5 typical specification

Bead diameter1.6–2.5 mm
CO adsorption*≥28 ml/g
N₂ adsorption*≥11 ml/g
Static water adsorption*≥25 wt%
Average crush strength≥35 N
Bulk density0.73–0.78 g/ml

JLWN5 vs. Conventional 5A molecular sieve

Both materials are 5A molecular sieves. JLWN5 is engineered specifically for hydrogen PSA and a performance focus on the impurities that matter in hydrogen-rich streams.

See the material difference behind the PSA result.

Comparison pointConventional 5AJLWN5 5A molecular sieve
Adsorption focusGeneral 5A adsorption performance for standard separation duties.Developed for enhanced CO, N₂ and CH₄ adsorption in PSA hydrogen purification.
Hydrogen PSA roleCan be used as a 5A adsorbent layer, depending on the bed design.Dedicated hydrogen PSA molecular sieve for the CO/N₂/CH₄ removal task.
Cycle responseDepends on the selected grade and operating conditions.Designed for fast adsorption and desorption in cyclic PSA operation.
Average crush strengthApprox. 35 N average

Typical: 30–40 N

Typical average crush strength ≥35 N
CO adsorptionApprox. 28 ml/g average

Typical: 28–30 ml/g

≥28 ml/g

760 mmHg, 25°C, activated

N₂ adsorptionApprox. 10.4 ml/g average

Typical: 10–11 ml/g

≥11 ml/g

760 mmHg, 25°C, activated

CORE MATERIAL

Performance that helps keep hydrogen PSA units operating at their best

01 SELECTIVITY

Capture key residual impurities.

JLWN5 is designed for CO removal from hydrogen-rich streams, as well as N₂ and CH₄ adsorption—important separation tasks in hydrogen PSA applications.

02 FAST CYCLING

Keep pace with rapid PSA operation.

Fast adsorption and desorption characteristics help the material respond efficiently as PSA beds alternate between adsorption and regeneration.

03 MECHANICAL STRENGTH

Built for repeated pressure swings.

High crush strength helps limit bead breakage and dust generation, supporting stable operation in demanding cyclic service.

Find the best fit for your unit. Share your feed-gas composition, operating conditions and target hydrogen specification with our technical team for application-focused material guidance.

PROJECT CASE STUDIES

PSA case studies from real industrial operations

See how JALON molecular sieves have been applied in industrial PSA operations—from hydrogen purification upgrades to CO separation. The outcomes below are specific to the individual projects and operating conditions.

PSA hydrogen purification upgrade at a coal-tar hydrogenation workshop

During a technical upgrade, the site replaced the molecular sieve in its PSA hydrogen-production unit with a JALON hydrogen-purification molecular sieve. The unit completed commissioning in one attempt.

+7%

Hydrogen production rate increase

23,000 m³/h

Hydrogen production achieved

<1 ppm

CO content in hydrogen after upgrade

PSA CO separation at Yulin Coal Chemical.

JALON JLCOS adsorbent was applied in the first PSA stage for CO production.

104 t

Total adsorbent loading

22

Adsorption towers

18,000 m³/h

Second-phase processing volume

JLCOS

Adsorbent applied

PROJECT SCOPE
WHY JALON

A dependable partner from material qualification to global delivery

JALON combines specialized molecular-sieve development with quality-controlled production and responsive technical support for industrial gas separation applications.

28+

Years of molecular sieve technology and manufacturing experience.

68,000t

Annual shaped molecular sieve production capacity.

86+

Regions and countries served across industrial markets.

200g

Sample retained from every batch for three-year traceability.

Certifications that support consistent quality

ISO-certified management systems help ensure responsible manufacturing, documented quality control and reliable supply.

Frequently Asked Questions

JALON supplies molecular sieve adsorbents and application-focused technical support. We do not manufacture or supply complete PSA hydrogen purification skids, adsorption vessels, valves, control systems or packaged adsorption equipment. We support plant owners, EPCs and PSA equipment partners with material selection, qualification and supply based on feed composition, operating conditions, bed configuration and target hydrogen specification.

5A is not the only adsorbent used in hydrogen PSA. A layered bed may also use 3A, 4A, 13X, activated alumina or activated carbon for dehydration, CO₂ management or hydrocarbon protection, depending on the feed. 5A is commonly selected for the CO and N₂ removal stage. JLWN5 takes this role further with a binderless 5A structure designed for enhanced CO, N₂ and CH₄ adsorption, rapid cycling and high mechanical strength.
Hydrogen-rich feed gas can contain CO, CO₂, N₂, CH₄, water vapor and residual hydrocarbons. PSA uses adsorbents with different affinities to retain these impurities while hydrogen passes through as product gas.
PSA is commonly used after steam methane reforming and with refinery, petrochemical, coke oven, methanol and ammonia off-gases. Suitability depends on gas composition, operating pressure and the required hydrogen purity and recovery.
Review the feed-gas analysis, bead size, bed layout, loading method, operating pressure and temperature, cycle timing, current hydrogen specification and any signs of bed attrition or contamination.
Changes in feed composition, moisture or heavy-hydrocarbon carryover, adsorbent attrition, bed settling and process-cycle changes can all affect performance.

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JALON JLOED MOLECULAR SIEVES USED FOR ELECTROLYTE DEHYDRATION

This letter is to inform you that we evaluated Molecular Sieve JLOED 3.0-5.0 MM product from Luoyang Jalon Micro-nano New Materials Co., Ltd to dry our organic solvents for production of electrolyte for Li ion battery. The resulting organic solvents that went through our process with the Molecular Sieve JLOED 3.0-5.0 MM product in our R/D and production facility located in Chico, CA, US passed our specifications showing extremely low content of moisture, below 10ppm. This Molecular Sieve product met our quality requirement, and it is highly recommended for use in the industry of Li ion battery for drying of organic solvents. We also appreciate the technical support from the company.

Nanotech Energy

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